Part of my PhD involved lots of fluoride synthesis using HF. I always used gloves (changing them very frequently). My advisor never used them for the following reason: if a droplet of HF lands on your glove you won't notice, but HF will go through the glove. If it lands on your bare hand chances are you'll notice it and wash them immediately. I could never follow his advise, but I did change gloves pretty much every step in the synthesis just in case.

I’m definitely in the frequent glove change camp. And PSA for anyone reading this, latex gloves are worse than useless for protection against HF. But hopefully anybody working with HF already knows that.