The actual "make it go bang" bit here isn't the most potent. (I think I have capacitors here which wouldn't care in the least about this, despite their datasheet ratings.)

If you need to take it to the next level, consider something based on a xenon photoflash driver. These aren't as common as they used to be, but they're still not hard to make. I had to make one of these a while back and ended up using one of those $5 LTC chips but that was appropriate for the situation; there are certainly other ways to do it. This will basically charge a 400V capacitor up for you, which you can then dump into the 5V part. High-quality 5V capacitors will handle small spikes of this. But using a big 400V capacitor will make a big spike, which is not kind to the other capacitor. (I must confess I didn't try blowing up a lot of things on the one I made, but it was medical test gear, not technically a capacitor-blower-uper, and I was on deadline anyway. I also had other, significantly more destructive, equipment available to me should that be the goal.)