Firefox doesn't ask permission just to use localstorage, no modern browser does this. The closest thing you get is when a site wants to persist storage with "navigator.storage.persist()", which should prompt you for permission. But localstorage data usually persists anyway, and only gets deleted if the browser's storage is "under pressure", so I've never personally worked on a site or web app that had to use that API.

You mean by default or it cannot be configured that way? I believe, I had Chrome configured to not allow storage by default, only for sites I added to an exclusion list. I cant remember now, but isnt there also an option to change the default on Firefox to deny or always ask for permission?