Except quotation marks look like regular text. I regularly use quotes in prompts for, ya know, quotes.

The GP isn't suggesting to literally use quotes as the delimiter when prompting LLMs. They're pointing out that we humans already use delimiters in our natural language (quotation marks to delimit quotes). They're suggesting that delimiters of any kind may be helpful in the context of LLM prompting, which to me makes intuitive sense. That Claude is using XML is merely a convention.