The Library of Congress very generously provides a scan of the Paul Carus translation [1].

The transliteration of the Tao starts on page 159 and consists of columns of the characters each with a literal meaning and occasional comments by the translator. I found the first few chapters in that presentation very interesting, like a kind of puzzle (I don't read Chinese to any extent at all).

[1] https://www.loc.gov/item/34009062/