I'm not sure about Gurobi or how the author used it in this case. But in general, yes: these combinatorial solvers construct proof trees showing that, no matter how you assign the variables, you can't find a better solution. In simpler cases you can literally inspect the proof tree and check how it's reached a contradiction. I imagine the proof tree from this article would be an obscenely large object, but in principle you could inspect it here too.