>"Unicode Scalars", aka "well-formed UTF-16", aka "the Python string type"

"the Python string type" is neither "UTF-16" nor "well-formed", and there are very deliberate design decisions behind this.

Since Python 3.3 with the introduction of https://peps.python.org/pep-0393/ , Python does not use anything that can be called "UTF-16" regardless of compilation options. (Before that, in Python 2.2 and up the behaviour was as in https://peps.python.org/pep-0261/ ; you could compile either a "narrow" version using proper UTF-16 with surrogate pairs, or a "wide" version using UTF-32.)

Instead, now every code point is represented as a separate storage element (as they would be in UTF-32) except that the allocated memory is dynamically chosen from 1/2/4 bytes per element as needed. (It furthermore sets a flag for 1-byte-per-element strings according to whether they are pure ASCII or if they have code points in the 128..255 range.)

Meanwhile, `str` can store surrogates even though Python doesn't use them normally; errors will occur at encoding time:

  >>> x = '\ud800\udc00'
  >>> x
  '\ud800\udc00'
  >>> print(x)
  Traceback (most recent call last):
    File "<stdin>", line 1, in <module>
  UnicodeEncodeError: 'utf-8' codec can't encode characters in position 0-1: surrogates not allowed

  >>> x.encode('utf-16')
  Traceback (most recent call last):
    File "<stdin>", line 1, in <module>
  UnicodeEncodeError: 'utf-16' codec can't encode character '\ud800' in position 0: surrogates not allowed

  >>> x.encode('utf-16-le', 'surrogatepass')
  b'\x00\xd8\x00\xdc'

  >>> y = x.encode('utf-16-le', 'surrogatepass').decode('utf-16-le')
  >>> y
  '𐀀'
  >>> len(y)
  1
  >>> ord(y)
  65536

  $ cat cmdline.py 
  #!/usr/bin/python
  
  import binascii, sys
  for arg in sys.argv[1:]:
      abytes = arg.encode(sys.stdin.encoding, 'surrogateescape')
      ahex = binascii.hexlify(abytes)
      print(ahex.decode('ascii'))
  $ ./cmdline.py foo
  666f6f
  $ ./cmdline.py 日本語
  e697a5e69cace8aa9e
  $ ./cmdline.py $'\x01\x00\x02'
  01
  $ ./cmdline.py $'\xff'
  ff
  $ ./cmdline.py ÿ
  c3bf

  >>> b'\xff'.decode('utf-8')
  Traceback (most recent call last):
    File "<stdin>", line 1, in <module>
  UnicodeDecodeError: 'utf-8' codec can't decode byte 0xff in position 0: invalid start byte
  >>> b'\xff'.decode('utf-8', 'surrogateescape')
  '\udcff'