| ▲ | barbazoo 5 days ago |
| What about from an environmental standpoint if we think about that these Lithium--Ion batteries will have to be replaced and recycled every (as the article says, not sure if true) <12 years. We have a history of not pricing in negative externalities, did we do that this time? |
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| ▲ | epistasis 5 days ago | parent | next [-] |
| > environmental standpoint if we think about that these Lithium--Ion batteries will have to be replaced and recycled every I am very interested in this question, but those who raise it never have answers about the negative impacts of mining lithium. For example, the amount of lithium needed for an EV is an order of magnitude less than the amount of steel needed. What is so bad about lithium mining that it's 10x worse than iron mining, pound for pound? Nobody has ever answered my request for environmental concerns with a concrete environmental lithium mining concern, such as acidification that can sometimes happen with iron mining. I've researched and researched, found nothing, which leaves me thinking that the worst case scenario for lithium is no worse than the worst case for iron. Meanwhile, we have such immense documented harms from fossil fuel extraction that nobody ever questions again, or with the same intensity that's reserved for supposedly toxic lithium batteries. The apparent benefit is massive, so any delay seems to cause massive harm to the environment. I think we need to flip the question: where is the proof that coal/oil/iron is better for the environment than mining and recycling batteries? (BTW, it's at least 20 years now for grid batteries, with lifetime going up all the time...) |
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| ▲ | bcrosby95 5 days ago | parent | next [-] | | Any analysis of EVs vs ICE cars I've seen put EVs at 1.5-2x the carbon footprint to produce, but win out in the long run. My default assumption has always been it comes from the battery pack - I'm not sure what else could cause such a difference. | | |
| ▲ | cr125rider 5 days ago | parent [-] | | And the cross over point is surprisingly fast: https://youtu.be/6RhtiPefVzM?si=ITsJsHAKjYtMNZEc | | |
| ▲ | epistasis 5 days ago | parent [-] | | People don't realize the massive amount of emissions from using their car because they don't see the massive amount of material they put into their car every time they fuel up. A 20 gallon tank produces 400 pounds of CO2 for every fill up. Even manually filling a tank by lifting a series of five gallon containers would seriously reorient the average person's conception of their fuel usage. | | |
| ▲ | bcrosby95 5 days ago | parent | next [-] | | Yeah, and the most deceptive thing is that burning 1 lb of gasoline produces about 3 lbs of CO2. | |
| ▲ | 5 days ago | parent | prev [-] | | [deleted] |
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| ▲ | smithkl42 5 days ago | parent | prev | next [-] | | My understanding (bowing to ChatGPT) is that you can get 1 pound of iron from <2 pounds of iron ore. But to get 1 pound of lithium, you need around 500 pounds of lithium ore. So if an electric car requires 2000 pounds of iron and 50 pounds of lithium, that works out to 4000 pounds of iron ore that needs to be mined and refined, vs 25,000 pounds of lithium ore. | | |
| ▲ | epistasis 5 days ago | parent | next [-] | | Interesting, but tailings never seem to enter much into environmental analyses that I have seen, unless you count coal ash as "tailings" which would be a pretty broad interpretation of the idea. Lithium is also extracted via brine, as opposed to hard rock. Most of the environmental reporting has been on the brine approaches, which currently are in high elevations of South American mountains, and the problem appears to be mostly the use of land and taking that land out of the ecosystem for economic use as drying pools. But the same problem occurs with mining, too! | |
| ▲ | trhway 5 days ago | parent | prev | next [-] | | >So if an electric car requires 2000 pounds of iron and 50 pounds of lithium, that works out to 4000 pounds of iron ore that needs to be mined and refined, vs 25,000 pounds of lithium ore. means recycling of lithium batteries will be a thriving business. (i.e. big difference from recycling of say tires or plastic bottles, more like, pretty successful, recycling of aluminum, and even better than it) | | |
| ▲ | numpad0 5 days ago | parent [-] | | Li-ion batteries are older than you think. First volume production of NMC cells happened 1991. LFP in 1997. Google was founded 1998. No one made fortune in Li-ion recycling in all those years. Li-ion cells remained disposable. | | |
| ▲ | adrianN 5 days ago | parent | next [-] | | Lithium cells are still disposable (eg vapes). The difference is that a single EV contains hundreds of kilograms are we are not used to just chucking old cars in the gutter. | |
| ▲ | HeadsUpHigh 5 days ago | parent | prev [-] | | The volume of batteries wasn't there, neither did we really have the network to sell scrap batteries like we do with used cars. |
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| ▲ | kragen 5 days ago | parent | prev [-] | | You shouldn't post AI slop here. Until a few years ago, no lithium was mined from ore. Now roughly half of it is, mostly spodumene, LiAl(SiO3)2, which you can easily calculate (with units(1)) is 3.7% lithium, 18 times higher than the 0.2% you're claiming. 50 pounds of lithium thus comes, on average, from 25 pounds of brine-derived lithium and 670 pounds of spodumene. | | |
| ▲ | adrian_b 5 days ago | parent [-] | | While the rest of what you say is right, you will not find anywhere on Earth a mine with compact spodumene. Spodumene is dispersed among other minerals into rocks and it only forms a few percent at most of those rocks, if not only fractions of a percent. The rocks must be crushed and spodumene must be separated from the other much more abundant minerals, by flotation or similar mineral concentration techniques, before going further to chemical processing. So your 670 pounds must be multiplied by a factor like 100, varying from mine to mine. Some multiplication factor must also be used for the iron ore, which is also mixed with undesirable silicates, but iron oxide may reach up to a few tens of percent of the rock, so the multiplication factor is much smaller. | | |
| ▲ | kragen 5 days ago | parent [-] | | Hmm, I thought the Australian deposits were mostly spodumene. I appreciate the correction, although it's embarrassing; I'd rather be embarrassed than wrong. | | |
| ▲ | nandomrumber 4 days ago | parent [-] | | At the mine's current size, it can fulfil a third of the worldwide demand for lithium spodumene concentrate,[1] which is used to produce lithium hydroxide, a component of lithium-ion batteries. https://en.wikipedia.org/wiki/Greenbushes_mine | | |
| ▲ | kragen 4 days ago | parent [-] | | Further down on the page, it says: > The mine sets a chemical-grade specifications benchmark of 6.0% Li2O minimum and 0.8% Fe2O3 maximum. Spodumene is 0% iron. How much lithium does it contain on a Li2O basis? 8%, I think: You have: lithium + aluminum + 2(silicon + 3 oxygen)
You want:
Definition: 186.089
You have: (2 lithium + oxygen) / 2 _
You want: %
* 8.0282762
/ 0.12455974
That suggests that the rock (pegmatite?) being mined there is about 75% spodumene. Is it possible that this is a misinterpretation, perhaps describing a standard for the output of the froth flotation process or similar, and the rock being dug up really is just a few percent spodumene?No, as it turns out. The paper linked just before that says that none of the rock is quite that lithium-rich https://pubs.geoscienceworld.org/segweb/economicgeology/arti...: > The lithium ore zones comprise mainly spodumene, apatite, and quartz, with some ore zones returning upward of 5 percent Li2O. OTOH, that paper is from 01995, so maybe there are new findings since 30 years ago. It says the reserves there were 4% Li2O. Later in the paper, it explains: > The hanging-wall lithium zone in the main pegmatite is generally richer (up to 5% Li2O, equivalent to 60–80% spodumene) than the footwall lithium zone That seems to contradict adrian_b's strong statement: > Spodumene is dispersed among other minerals into rocks and it only forms a few percent at most of those rocks, if not only fractions of a percent. It could still be true at other mines. |
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| ▲ | 01HNNWZ0MV43FF 5 days ago | parent | prev [-] | | That's why hybrids are great, hedges your bets between iron and lithium | | |
| ▲ | eptcyka 5 days ago | parent | next [-] | | Non-plugin hybrids typically do not use lithium batteries. | | |
| ▲ | UncleOxidant 5 days ago | parent [-] | | Is this still the case? Haven't most of the manufacturers switched over from NiMH? | | |
| ▲ | eptcyka 5 days ago | parent | next [-] | | They are better suited for the usecase, as they can sustain far more charge cycles without degradation. Which you end up doing a lot. | |
| ▲ | senectus1 5 days ago | parent | prev [-] | | my 2023 Rav 4 is still NiMH |
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| ▲ | dzhiurgis 5 days ago | parent | prev [-] | | Terrible cars tho. Nobody likes their hybrids compared to pure EV. | | |
| ▲ | LoveMortuus 5 days ago | parent | next [-] | | I used to drive a Toyota Yaris Hybrid and I really liked it, I moved to a different country and couldn't take the car with me and now I drive a scooter, but if I'll ever buy a car again, it'll most likely be a hybrid, I really like the range. | |
| ▲ | spauldo 4 days ago | parent | prev | next [-] | | I like my Honda just fine. Granted, I've never owned an EV, but considering I travel a lot and gas stations are plentiful and fast, it's a better fit for me than an EV would be. I do think a plug-in hybrid would be better for when I'm not traveling, but I bought this car specifically for travel. | |
| ▲ | ash_091 4 days ago | parent | prev [-] | | Terrible in what sense? I had no complaints with my Prius C. | | |
| ▲ | dzhiurgis 3 days ago | parent [-] | | Slow and expensive to maintain. Takes a special person to appreciate that. |
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| ▲ | ziga 5 days ago | parent | prev | next [-] |
| I think 12 years is an underestimate. Lithium-ion batteries will degrade, but they still have usable capacity. There are Tesla Roadsters still going strong, 15 years in. And the battery cell chemistry has since shifted to LFP, which has longer cycle life. |
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| ▲ | 0cf8612b2e1e 5 days ago | parent [-] | | Furthermore, I would expect that an industrial battery is treated better than an EV. Optimal cooling/charging/discharge rates likely have a large impact on longevity. |
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| ▲ | conradev 5 days ago | parent | prev | next [-] |
| What do you think the negative externalities actually are? Off of the top of my head: mining, landfill. Same as other metals. If the processes to extract Lithium from recycling become cheap enough to compete with the prices of mined Lithium, then that happens. Processes still need to be invented/scaled for that to happen: the only real way to deal with damaged or charged cells that I know of is to deep freeze them, shred them, and then defrost them slowly. But in either case: Lithium is going to end up as waste. Making it cheaper to make cars affordable and the grid more stable means that disposable batteries will be even cheaper. I don’t know how modern batteries fare in landfills: Most modern solar panels, for example, are relatively clean (mostly aluminum, silicon, copper, wee bits of lead). But not a waste management expert. |
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| ▲ | epistasis 5 days ago | parent [-] | | That's very interesting about the freezing. I wonder if Redwood Materials does that? https://www.redwoodmaterials.com/news/responding-recovering-... They've been working hard at recycling, and the biggest challenge at the moment is actually getting old batteries for the process. There's not many in-service batteries reaching end of life yet, so they mostly deal with production scrap. |
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| ▲ | jillesvangurp 5 days ago | parent | prev | next [-] |
| Some LFP batteries now get rated for 5000 or more cycles or more. Even if you cycle them fully every day, that's 14 years. And that's unlikely to be needed or happening. These might last decades. At which point, battery tech might be massively better. Also, even better batteries might be on the way. E.g. Sodium Ion would be a bit less energy dense and have a similarly long life. It doesn't contain any lithium and could be cheap to manufacture in a few years. The biggest driver here would be cost and other properties (like how quickly can it deliver the power and at what capacity). |
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| ▲ | XorNot 5 days ago | parent | next [-] | | It's irrelevant how long they last unless is starts to substantially exceed human lifespans though. 10 years or 20, eventually every product you put out there is replaced and you enter the steadystate waste phase of X tons per year. Personally of course, I don't think this matters at all: old lithium batteries degrade into salt and don't contain harmful chemicals. There's no real indication we'd ever have a problem dealing with them, even if it was just throwing them all into a big hole till the hole looks enough like a natural lithium source to mine again. | | |
| ▲ | tonyedgecombe 4 days ago | parent [-] | | >It's irrelevant how long they last unless is starts to substantially exceed human lifespans though If a product has twice the lifetime then you are going to have half the waste. I'm not sure how that is irrelevant. | | |
| ▲ | XorNot 4 days ago | parent [-] | | Or you'll have twice the product in circulation because you might be far below satisfying actual demand. For batteries this is definitely true: we're not even close to storing weeks worth of every yet, and the more you can store the more flexible and useful they become. |
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| ▲ | leptons 5 days ago | parent | prev [-] | | Lithium batteries last as long as one battery out of thousands decides to thermal runaway, and then you have to replace all of them (as well as the facility they were all housed in). | | |
| ▲ | conradev 4 days ago | parent | next [-] | | It’s pretty hard to make one of these solid state blades catch fire: https://youtu.be/CGQwqWqzkNA | |
| ▲ | pabs3 5 days ago | parent | prev [-] | | Does that happen with LFP? It is supposed to be safer. | | |
| ▲ | jillesvangurp 5 days ago | parent [-] | | In short no. LFP is very safe. People have done tests involving shotguns, flamethrowers, hammers/nails, etc. And while that destroys the battery, they don't tend to explode, combust, burn uncontrollably, etc. These are nice party tricks with predictable outcome if you understand the chemistry (it's inherently safe). |
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| ▲ | ysofunny 5 days ago | parent | prev | next [-] |
| > We have a history of not pricing in negative externalities, did we do that this time? I worry the answering that question requires answering this question: whose negative externalities? |
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| ▲ | fragmede 5 days ago | parent [-] | | Humanity's. We've only got one Earth, and if my factory can just dump toxic waste down the drain which flows right to the bay and kills all the fish, for free, why would I pay for it when I could be spending that money on a yacht? | | |
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| ▲ | brandonagr2 5 days ago | parent | prev | next [-] |
| What is the negative externality of recycling batteries? That is way better than having to mine minerals out of the ground, eventually there won't need to be any significant mining and all the battery minerals will be in a constant cycle of being used then recycled |
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| ▲ | barbazoo 5 days ago | parent | next [-] | | I know very little of chemistry and how batteries are produced, so from that level I'm imagining that once a battery is deemed to have reached end-of-life, it will have to get shipped somewhere, be recycled/refurbished for which presumably we will need some new material which needs to be mined, shipped, etc. All that requires water, produces waste that may or may not be toxic, the metals may come from places lacking human rights, and takes energy which may or may not be clean [1]. So all this could in the end have a considerable amount of negative externality somewhere. What I like that I'm hearing about this CO2 battery, whether true will have to be seen, is that it might rely on off the shelf components, that's great, means the supply chain can be simple, and has longer life in the first place. And that while potentially even cheaper? [1] https://www.youtube.com/watch?v=GSzh8D8Of0k | | |
| ▲ | tehjoker 5 days ago | parent [-] | | This is cool, but one thing to consider is that you're not going to be getting that CO2 from the atmosphere, but from captured emissions. When that plant is decomissioned, the path of least resistance is to just vent it. | | |
| ▲ | SoftTalker 5 days ago | parent [-] | | If you've already got pure CO2 in a tank, sequestering it is a much easier problem. The hard part is capturing it out of smokestack emissions or (especially) directly from the atmosphere as it's much more diffuse. |
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| ▲ | throwaway3b03 5 days ago | parent | prev | next [-] | | Except that the recycling ... cycle is not perfect. Far from it. I'd reckon maybe half of all lithium ends up in recycling. Other half probably ends up in the landfill. For instance, I picked up a broken ebike from the trash not long ago (Amsterdam). Battery still in it. Same goes for lots of smaller electronics. | | |
| ▲ | nicoburns 5 days ago | parent | next [-] | | That's true, but seems unlikely to be an issue for EV batteries. Cars are large and valuable enough that there are established businesses that deal with scrapping them. | |
| ▲ | cogman10 5 days ago | parent | prev [-] | | That changes rapidly as EVs and grid storage take off. 99+% of those will be recycled and those will make up the bulk of lithium battery consumption. |
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| ▲ | slow_typist 5 days ago | parent | prev | next [-] | | You will not get back 100 % of the raw material in any economically feasible process though. If your process gets 90% of the lithium out of the battery, after 7 cycles more than half of the lithium is gone. Therefore Mining can’t stop even when the market doesn’t grow anymore. | | |
| ▲ | matthewdgreen 5 days ago | parent | next [-] | | Current BESS are rated to last 10-15 years. Battery makers are already moving to lithium-free sodium chemistries. It's hard to imagine what we'll be using at the end of seven full cycles (70-105 years from now.) Sodium? Tiny fusion reactors? Firewood and charcoal? Yes, we should care about this and try to leave our descendants with good solutions. No, we should not think about it so much that we leave our descendants with a devastatingly acidified ocean and uninhabitable equatorial regions in the process of worrying about it. | | | |
| ▲ | epistasis 5 days ago | parent | prev [-] | | The process of battery manufacturing is always improving, getting more storage with less lithium. So when a battery is recycled, it will actually produce more battery than the original battery, even with lithium losses. We don't know how long that process will go on, but in any case the amount of lithium needed will be a steady state, assuming constant need for batteries. But much more likely we will see ever increasing demand for batteries, just as we do for steel or copper or whatever minerals power our current economy. | | |
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| ▲ | 5 days ago | parent | prev [-] | | [deleted] |
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| ▲ | thelastgallon 4 days ago | parent | prev [-] |
| You want to price in negative externalities for lithium because we didn't price in negative externalities for fossil fuels? Am I understanding you right? |