Most Intel/AMD CPUs do the same thing for a few alternative instructions, e.g. "sub rax, rax".

I do not think that anyone bothers to do this for a "mov eax, 0", because neither assembly programmers nor compilers use such an instruction. Either "xor reg,reg" or "sub reg,reg" have been the recommended instructions for clearing registers since 1978, i.e. since the launch of Intel 8086, because Intel 8086 lacked a "clear" instruction, like that of the competing CPUs from DEC or Motorola.

One should remember that what is improperly named "exclusive or" in computer jargon is actually simultaneously addition modulo 2 and subtraction modulo 2 (because these 2 operations are identical; the different methods of carry and borrow generation distinguish addition from subtraction only for moduli greater than 2).

The subtraction of a thing from itself is null, which is why clearing a register is done by subtracting it from itself, either with word subtraction or with bitwise modulo-2 subtraction, a.k.a. XOR.

(The true "exclusive or" operation is a logical operation distinct from the addition/subtraction modulo 2. These 2 distinct operations are equivalent only for 2 operands. For 3 or more operands they are different, but programmers still use incorrectly the term XOR when they mean the addition modulo 2 of 3 or more operands. The true "exclusive" or is the function that is true only when exactly one of its operands is true, unlike "inclusive" or, which is true when at least one of its operands is true. To these 2 logical "or" functions correspond the 2 logical quantifiers "There exists a unique ..." and "There exists a ...".)